Abstract

It has been described the development of electrochemical nano sensor for the detection of mercury ions from aqueous solutions based on the formation of polyaniline nanoparticle films. Screen printed carbon electrodes were modified with polyaniline nanoparticles. Electropolymerization of polyaniline nanoparticles was performed by the pulsed potentiostatic method. The sample of polyaniline nanoparticles was prepared by repeating the potential step process three times. Structural and morploigcal characterization of polyaniline nanoparticles modified screen printed carbon electrode was performed using Fourier Transmission infrared (FTIR), X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). PANI nanoparticles were spherical shaped having an apparent dimeter varying from 20 to 45 nm. Square wave anodic stripping voltammetry was used for the detection of Hg(II) on PANI NPs modified screen printed carbon electrode under optimized conditions. Hg(II) was deposited for 60 seconds by the reduction of Hg(II) in buffer solution:(citric acid and sodium chloride pH 2.30), followed by Hg stripping between 0.3 and 0.8 V at the following parameters: Scan rate: 100 mV s-1, frequency: 60 Hz, amplitude: 0.025 V and increment: 4.0 mV. it was found that the PANI NPs modified screen printed carbon electrode had a highest anodic stripping peak current in solution of pH 2.30. The limit of detection value for Hg(II) was found to be 2.50 ± 0.03 ppb. The limits of detections determined are below the corresponding guideline value from the World Health Organization (WHO). In addition, the modified nano electrode exhibited excellent reproducibility and high stability. The developed method was successfully applied to determine Hg(II) in real water samples with satisfactory results.

The present research was implemented to analyses the seedling tolerance of three species Eucalyptus gomphocephala DC (Myrtaceae) (common name 'Tuart'), Eucalyptus marginata Sm. (common name 'Jarrah') and Corymbia calophylla (Lindl.) K.D. Hill & J. A. S. Johnson (common name 'Marri') to soil-induced stressor, namely soil alkalinity (limestone). Seeds germinated in shallow trays filled with white sand in a naturally lit glasshouse (control treatment). A liming treatment was conducted with 20% w/w crushed and sifted Tomala limestone adds to potting mix to increase soil pH. The experiment was conducted over 82 days. E. gomphocephala is restricted soils overlying limestone on study area and according to total seedling dry weight data and calculated relative growth rates coped best in a limestone-enriched soil. However, when examining all the growth and physiological data collected C. calophylla appeared to be the middling tolerant, with no significant difference in leaf allocation or leaf water loss between the well-watered controls and the limestone-enriched treatments whereas the E. marginata was the least tolerant with a 14% reduction in stomatal conductance. 

infected organs mainly liver and lungs and to some extent other organs including spleen, kidneys, heart, brain and bones of the animal carcasses. Prevention of cystic hydatid disease primarily focusing on veterinary investigations for controlling the extent and the intensity of echinococcosis in the definitive host populations, which indirectly may lead to control the prevalence of hydatid disease in the intermediate host animals. Treatment of cystic hydatidosis in livestock is still under investigation but anti-helminthes drugs can be used. Regular treatment, taking high degree of precautions when handling pets or dealing with animal meat must be taken into consideration to minimize the level of infection and egg excretion as well as the vaccination of ruminant intermediate hosts, are all in evaluation.

Bacillus thuringiensis subsp. israelensis is the most important biological insecticide for the control of mosquito vectors of disease. This bacterium produces toxins during sporulation that cause larval death by lysis of cells in their midgut. The pBtoxis plasmid of B. thuringiensis subsp. israelensis encodes all the mosquitocidal toxins and a number of other coding sequences. The plasmid also carries potential germination genes organised in a single ger operon. Comparison of the germination responses of spores from strains with and without pBtoxis revealed that this plasmid could promote activation of the spores under alkaline conditions but not following heat treatment. Introduction of the ger operon on a recombinant plasmid to the plasmidless strain established this operon as the first with an identified role in alkaline activation.

Research was conducted at Curtin University (Western Australia) to assess the seedling tolerance of three species Eucalyptus, gomphocephala DC (Myrtaceae) (common name ‘Tuart’), Eucalyptus marginata Sm. (common name ‘Jarrah’) and Corymbia calophylla (Lindl.) K.D. Hill & J. A. S. Johnson (common name ‘Marri’) to soil-induced stressor, namely water loggings (flooding). Flooding treatment was achieved by filling the tubs with water, approximately 1 cm above the soil surface and control treatment had the same method except with drainage holes. Study assessment was attained by statistical change in seedling growth, leaf allocation and leaf physiology after 70 days of seed germination. Tolerance was assessed by measuring changes in seedling growth, leaf allocation and leaf physiology after 70-80 days. C. calophylla was the most tolerant to prolonged waterlogging (80% survival, no difference in transpiration rates); E. marginata was the least tolerant (10% survival, 95% decrease in transpiration rate). E. marginata was the least tolerant to the three soil stresses. E. marginata prefers habitats that are not excessively wet on well-drained soils. C. calophylla was the most tolerant, occurring and tolerating wet, well-drained soils and thus demonstrated better physiological responses of three prominent studied eucalypts to soil-induced stresses provides us with invaluable knowledge for rehabilitating and restoring urban bush land.tolerance to prolong waterlogging. Knowing the seedling growth and

The present paper involves a detailed comparison between the salt tolerance and physiological responseof three eucalypt species occurring within the Swan Coastal Plain, Western Australia. Eucalyptus gomphocephala DC (Myrtaceae) (common name ‘Tuart’) is restricted to the calcareous (limestone), brown or yellow sand of the coastal Spearwood dunes. Eucalyptus marginata Sm. (common name ‘Jarrah’) is a small tree on the porous, well-drained sandy soils of the Bassendean dunes Plain, and a much larger tree on the Darling Range. Corymbia calophylla (Lindl.) K.D. Hill & J. A. S. Johnson (common name ‘Marri’), and has a similar distribution to that of Jarrah, but is more common on wetter, well drained soils. This investigate implemented to find out the seedling tolerance of these three species to soil-induced stressor, namely salinity via addition of sodium chloride solution. Tolerance assessment measured changes in seedling growth, leaf allocation and leaf physiology after 70-80 days. Neither E. marginata and C. calophylla could tolerate the highest salinity (0.25 M NaCl solutions) with 9-13% survival, although E. marginata was clearly the least tolerant with 52% reduction in relative growth rate and a 88% in transpiration rates. E. gomphocephala was the most tolerant to salt stress in terms of survival and growth parameters. 

The title complex was isolated as a red solid from the reaction of 4-(salicylaldiminato)antipyrine, HL, and cobalt (II) acetate in ethanol. The complex has been characterized by elemental analysis, FTIR, UV-Vis, and X-ray single crystal diffraction. Two crystallographically different cationic units, A and B, of the title complex are found. Both units are essentially isostructural; nevertheless, small differences exist between them. Both units contain four cobalt atoms arranged at the corners of distorted cubane like core alternatively with phenoxy oxygen of the Schiff base. In both cases, one cobalt binds to three coordinated sites from the corresponding tridentate Schiff base ligand, and the fourth one was bonded by the acetate oxygen, and the fifth and the sixth donor sites come from the phenolate oxygen of another Schiff base ligand.

Network layer indications are not readily available upon a link change; therefore, general dependes on the network layer may introduce unnecessary delays due to network layer signaling for a simple link layer handover. If information could be gathered at link layer to determine the need for network layer signaling, then both the delay and signaling load could be really improved over the current standards of Mobile IP.

This paper presents a Cross-layer decision on two layer network and link layers to improve the performance of Enhanced Mobile IP (E-Mobile IP) handover in which reducing packet loss and latency during handover process.